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Synlett 2024; 35(13): 1545-1550
DOI: 10.1055/a-2205-5806
DOI: 10.1055/a-2205-5806
letter
Silver Nitrate Catalyzed Sulfonylation of O-Propargyl Alkynes
We gratefully acknowledge the Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES), the Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq, Grant Numbers 302829/2022-9 and 405052/2021-9), and the Fundação de Amparo à Ciência e Tecnologia do Estado de Pernambuco (FACEPE, Grant Numbers APQ-0436-1.06/22, IBPG-0009-1.06/19, and BFP-0039-1.06/22) for financial support.
Abstract
The development of new catalytic methods based on lower-cost metals under environmentally friendly conditions is still a challenge. Herein, we report an efficient strategy for the synthesis of vinyl sulfones from O-propargyl alkynes and sodium salts of sulfinic acids using silver nitrate, an inexpensive and readily available catalyst, under air atmosphere using aqueous conditions. The products were obtained in good to moderate yields, and the mechanism of the reaction was also investigated.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-2205-5806. Additional experimental procedures and copies of 1H and 13C NMR spectra (PDF) are included.
- Supporting Information
Primary Data
- Primary Data
Primary data for this article are available online at https://doi.org/10.5281/zenodo.10305429 and can be cited using the following DOI: 10.5281/zenodo.10305429.
Publication History
Received: 02 August 2023
Accepted after revision: 07 November 2023
Accepted Manuscript online:
07 November 2023
Article published online:
14 December 2023
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