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Synlett
DOI: 10.1055/a-2579-3319
letter

Nickel-Catalyzed Nucleophilic Substitution of Cyclopropenes by Secondary phosphines

Hua-su Fang
1   Department of Chemistry, University of Science and Technology of China, Hefei, China (Ringgold ID: RIN12652)
,
Li-yan Yuwen
1   Department of Chemistry, University of Science and Technology of China, Hefei, China (Ringgold ID: RIN12652)
,
Ya-yu Qi
1   Department of Chemistry, University of Science and Technology of China, Hefei, China (Ringgold ID: RIN12652)
,
Jing-wen Wang
1   Department of Chemistry, University of Science and Technology of China, Hefei, China (Ringgold ID: RIN12652)
,
Qingwei Zhang 
2   chemistry, University of Science and Technology of China, Hefei, China (Ringgold ID: RIN12652)
› Author AffiliationsSupported by: NSFC 22071224,22471251
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The research on the efficient synthesis of allylphosphine compounds holds paramount significance. A nickel-catalyzed ring-opening of cyclo-propenes to synthesize allylphosphine compounds has been developed. This transformation allows for mild and efficient preparation of allylphosphine compounds in good yields, featuring 100% atom efficiency



Publication History

Received: 26 February 2025

Accepted after revision: 09 April 2025

Accepted Manuscript online:
09 April 2025

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