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Synthesis 2009(19): 3285-3292  
DOI: 10.1055/s-0029-1216953
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© Georg Thieme Verlag Stuttgart ˙ New York

Total Synthesis of (+)-Dodoneine and Its 6-Epimer

Gowravaram Sabitha*, Vangala Bhaskar, S. Siva Sankara Reddy, Jhillu S. Yadav
Organic Division I, Indian Institute of Chemical Technology, Hyderabad 500007, India
Fax: +91(40)27160512; e-Mail: gowravaramsr@yahoo.com;
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Publication History

Received 20 March 2009
Publication Date:
21 August 2009 (online)

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Abstract

The total synthesis of dodoneine and its 6-epimer is described­, using HKR of epoxide and reduction with SmI2 reactions as key steps, respectively.

Key words

dodoneine - epidodoneine - trimethylsulfonium iodide - HKR - SmI2 - RCM