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Synthesis 2010(2): 276-282
DOI: 10.1055/s-0029-1217121
DOI: 10.1055/s-0029-1217121
PAPER
© Georg Thieme Verlag
Stuttgart ˙ New York
Single-Step Conversion of Electron-Deficient Aldehydes into the Corresponding Esters in Aqueous Alcohols in the Presence of Iodine and Sodium Nitrite
Weitere Informationen
Received
17 August 2009
Publikationsdatum:
13. November 2009 (online)
Publikationsverlauf
Publikationsdatum:
13. November 2009 (online)
Abstract
The direct conversion of aldehydes into their corresponding esters in the presence of iodine and sodium nitrite in aqueous alcohols is reported. In all these reactions, alcohol serves as reactant and also as reaction medium. Almost quantitative yields were obtained with aldehydes containing electron-withdrawing substituents and heterocyclic aldehydes.
Key words
esterification - electron-deficient aldehydes - iodine - sodium nitrite - nucleophilic addition
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