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Synlett 1997; 12(12): 1406-1408
DOI: 10.1055/s-0030-1260180
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© Georg Thieme Verlag KG Stuttgart · New York

Suzuki Cross-Coupling of Carbohydrates: Synthesis of β-Arylmethyl-C-glycosides and Aryl-Scaffolded Trisaccharide Mimics

Carl R. Johnson, Brian A. Johns
  • Department of Chemistry, Wayne State University, Detroit, Michigan 48202-3489, USA, Fax: (313)-577-3585, e-mail: crj@chem.wayne.edu
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Publication History

Publication Date:
19 September 2011 (online)

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Abstract

β-1-C-Arylmethylglycoside derivatives of D-glucose and D-mannose have been synthesized using a mild hydroboration/Suzuki cross-coupling sequence. The scope and limitations of this methodology as well as its extension to the construction of aryl scaffolded trisaccharide mimics is described.

Key words

C-glycoside - hydroboration - Suzuki - carbohydrate - trisaccharide