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Synthesis 2012; 44(13): 1997-2004
DOI: 10.1055/s-0031-1291135
DOI: 10.1055/s-0031-1291135
paper
Synthesis of [(Arylselanyl)alkyl]-1,2,3-triazoles by Copper-Catalyzed 1,3-Dipolar Cycloaddition of (Arylselanyl)alkynes with Benzyl Azides
Further Information
Publication History
Received: 21 December 2011
Accepted after revision: 16 April 2012
Publication Date:
25 May 2012 (online)
Abstract
In the presence of catalytic amounts of copper salts and sodium ascorbate, various (arylselanyl)alkynes underwent click-type 1,3-dipolar cycloaddition reactions with a range of benzyl azides bearing electron-withdrawing or electron-donating groups to give a series of novel [(arylselanyl)alkyl]-1,2,3-triazoles. This click chemistry protocol is an efficient method for synthesizing new selenium–nitrogen compounds that are potentially useful in biological studies.
Key words
heterocycles - azides - alkynes - click reactions - selenium - cycloadditions - catalysis - copperSupporting Information
- for this article is available online at http://www.thieme-connect.com/ejournals/toc/synthesis.
- Supporting Information
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For selected examples, see:
For selected examples, see: