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Synlett 2013; 24(1): 29-32
DOI: 10.1055/s-0032-1317746
DOI: 10.1055/s-0032-1317746
letter
Catalytic Asymmetric Cyclopropanation with Diazooxindole
Further Information
Publication History
Received: 12 October 2012
Accepted after revision: 12 November 2012
Publication Date:
11 December 2012 (online)
![](https://www.thieme-connect.de/media/synlett/201301/lookinside/thumbnails/10.1055-s-0032-1317746-1.jpg)
Abstract
The first catalytic asymmetric cyclopropanation using styrene and diazooxindole was achieved with Rh2(S-PTTL)4. The reaction proceeded smoothly with 1 mol% catalyst loading to provide a good yield of the biologically important spiro-cyclopropyloxindole product with moderate to good enantioselectivity and excellent diastereoselectivity.
Supporting Information
- for this article is available online at http://www.thieme-connect.com/ejournals/toc/synlett.
- Supporting Information
-
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For reviews, see:
The total synthesis of welwitindolinone A isonitrile, see:
Example of racemic synthesis of spiro-cyclopropane oxindoles, see:
Example of racemic synthesis of spiro-epoxyoxindoles, see:
For the catalytic asymmetric symthesis of spiro epoxyoxindole, see:
For examples of Cu(I)-catalyzed enantioselective cyclopropanation, see:
For examples of Ru(II)-catalyzed enantioselective cyclopropanation, see:
For examples of Co(II)-catalyzed enantioselective cyclopropanation, see:
For examples of Rh(II)-catalyzed enantioselective cyclopropanation, see:
For selected examples of catalytic asymmetric cyclopropantion with aryl diazoacetates, see: