Copper/Silver-Mediated Decarboxylative Trifluoromethylation of α,β-Unsaturated Carboxylic Acids with CF3SO2Na

Jun Yin; Yaming Li; Rong Zhang; Kun Jin; Chunying Duan

doi:10.1055/s-0033-1338578

Synthesis, Table of Contents

Synthesis 2014; 46(05): 607-612
DOI: 10.1055/s-0033-1338578

paper

Copper/Silver-Mediated Decarboxylative Trifluoromethylation of α,β-Unsaturated Carboxylic Acids with CF₃SO₂Na

Jun Yin

State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024, P. R. of China Fax: +86(411)84986295 Email: ymli@dlut.edu.cn

,

Yaming Li*

State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024, P. R. of China Fax: +86(411)84986295 Email: ymli@dlut.edu.cn

,

Rong Zhang

State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024, P. R. of China Fax: +86(411)84986295 Email: ymli@dlut.edu.cn

,

Kun Jin

State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024, P. R. of China Fax: +86(411)84986295 Email: ymli@dlut.edu.cn

,

Chunying Duan*

State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024, P. R. of China Fax: +86(411)84986295 Email: ymli@dlut.edu.cn

› Author Affiliations

Abstract

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Abstract

A copper/silver-catalyzed decarboxylative trifluoromethylation of α,β-unsaturated carboxylic acids with CF₃SO₂Na was performed under relatively mild conditions. The reaction shows high E/Z selectivity and wide substrate tolerance. Ag₂CO₃ plays an important role in promoting the decarboxylation process.

Key words

fluorine - transition metals - copper - catalysis - radicals

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References

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