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Synlett 2013; 24(10): 1211-1214
DOI: 10.1055/s-0033-1338837
DOI: 10.1055/s-0033-1338837
cluster
Structure and Reactivity of a Copper(I)-Fused N-Heterocyclic Carbene Complex: Reactivity toward Styrenic and Strained Alkenes
Weitere Informationen
Publikationsverlauf
Received: 15. April 2013
Accepted after revision: 30. April 2013
Publikationsdatum:
28. Mai 2013 (online)
Abstract
The synthesis of a fused N-heterocyclic carbene complex is accomplished using a flow-chemistry approach where a fused N-herterocyclic imidazolium chloride is passed through a packed bed of copper(I) oxide. The identity of the resulting complex is confirmed via crystal structure, and the reactivity is examined in the context of alkene hydroboration. We demonstrate that this novel complex can perform the desired reaction whereas the carbene ligand alone cannot.
Key words
boron - copper - flow chemistry - N-heterocyclic carbene complex - catalytic hydroboration - strained alkenesSupporting Information
- for this article is available online at http://www.thieme-connect.com/ejournals/toc/synlett.
- Supporting Information
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References and Notes
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