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Synthesis 2013; 45(15): 2070-2078
DOI: 10.1055/s-0033-1339188
DOI: 10.1055/s-0033-1339188
feature article
Ring-Expansion Reactions of Binaphthyl Azepines and Ferrocenophanes through Metal-Catalyzed [1,2]-Stevens Rearrangements
Weitere Informationen
Publikationsverlauf
Received: 04. April 2013
Accepted after revision: 14. Mai 2013
Publikationsdatum:
25. Juni 2013 (online)
Abstract
Enantiopure binaphthyl azocines can be prepared in a single step via the direct copper-catalyzed reaction of binaphthyl azepines and α-diazo carbonyl reagents. The [1,2]-Stevens rearrangement is general (61–93% yields) and can be extended to [3]ferrocenophanes; similar reactivity in favor of the products of ring expansion is obtained with these ferrocene derivatives (80–96% yields).
Supporting Information
- for this article is available online at http://www.thieme-connect.com/ejournals/toc/synthesis.
- Supporting Information
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