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Synlett 2013; 24(12): 1583-1587
DOI: 10.1055/s-0033-1339196
DOI: 10.1055/s-0033-1339196
letter
Oxidative Dearomatization of o-Hydroxymethylphenol and Intramolecular π4s+π2s Cycloaddition: An Expedient Synthesis of a Tricyclic Intermediate for Platencin
Further Information
Publication History
Received: 29 March 2013
Accepted after revision: 20 May 2013
Publication Date:
20 June 2013 (online)
Abstract
A synthesis of a tricyclic intermediate for platencin from a simple aromatic precursor is described. Oxidative dearomatization and intramolecular Diels–Alder reaction are key features of the approach.
Key words
oxidative dearomatization - intramolecular Diels–Alder reaction - cycloaddition - spiroepoxycyclohexa-2,4-dienoneSupporting Information
- for this article is available online at http://www.thieme-connect.com/ejournals/toc/synlett.
- Supporting Information
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