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Synthesis 2014; 46(02): 183-188
DOI: 10.1055/s-0033-1340287
DOI: 10.1055/s-0033-1340287
paper
Synthesis of N-Sulfonylamidines by Catalyst-Free Hydroamination of Ynamides and Amines
Weitere Informationen
Publikationsverlauf
Received: 25. September 2013
Accepted after revision: 28. Oktober 2013
Publikationsdatum:
22. November 2013 (online)
![](https://www.thieme-connect.de/media/synthesis/201402/lookinside/thumbnails/10.1055-s-0033-1340287-1.jpg)
Abstract
A novel synthesis of N-sulfonylamidines by catalyst-free hydroamination of N,N-disulfonyl ynamides with amines was developed. Alkyl amines react with N,N-disulfonyl ynamides under mild conditions, whereas aryl amines require higher temperatures. Plausible mechanisms are proposed to explain this reaction.
Supporting Information
- for this article is available online at http://www.thieme-connect.com/ejournals/toc/synthesis.
- Supporting Information
-
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