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Synlett 2014; 25(5): 736-740
DOI: 10.1055/s-0033-1340628
DOI: 10.1055/s-0033-1340628
letter
Nickel(0)-Promoted Carboxylation of Allenamides with Carbon Dioxide via a Nickelalactone Intermediate
Further Information
Publication History
Received: 21 November 2013
Accepted after revision: 18 December 2013
Publication Date:
29 January 2014 (online)

Abstract
Nickel(0)-promoted carboxylation of N-allenylamides (allenamides) with carbon dioxide proceeded via a nickelalactone intermediate to give β-amino acid derivatives. It was also found that the regioselectivity at the oxidative addition stage was strongly affected by the substituents on the allene part.
Supporting Information
- for this article is available online at http://www.thieme-connect.com/ejournals/toc/synlett.
- Supporting Information
-
References and Notes
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For reviews on transition-metal-promoted carboxylation, see:
For the most recent selected examples of transition-metal-promoted carboxylations, see:
For leading reviews on the chemistry of allenamide, see: