Synthesis 2014; 46(09): 1229-1235
DOI: 10.1055/s-0033-1340833
paper
© Georg Thieme Verlag Stuttgart · New York

Novel Nucleobase-Decorated Tripodands: Synthesis and Supramolecular Properties

Mirabela Ligia Golban
a   Babeş-Bolyai University, Supramolecular Organic and Organometallic Chemistry Center (SOOMCC), Cluj-Napoca, 11 Arany Janos str., 400028, Cluj-Napoca, Romania
,
Vlad Paşcanu
a   Babeş-Bolyai University, Supramolecular Organic and Organometallic Chemistry Center (SOOMCC), Cluj-Napoca, 11 Arany Janos str., 400028, Cluj-Napoca, Romania
,
Niculina D. Hădade
a   Babeş-Bolyai University, Supramolecular Organic and Organometallic Chemistry Center (SOOMCC), Cluj-Napoca, 11 Arany Janos str., 400028, Cluj-Napoca, Romania
,
Lidia Pop
a   Babeş-Bolyai University, Supramolecular Organic and Organometallic Chemistry Center (SOOMCC), Cluj-Napoca, 11 Arany Janos str., 400028, Cluj-Napoca, Romania
,
Crina Socaci*
a   Babeş-Bolyai University, Supramolecular Organic and Organometallic Chemistry Center (SOOMCC), Cluj-Napoca, 11 Arany Janos str., 400028, Cluj-Napoca, Romania
b   National Institute of Research and Development for Isotopic and Molecular Technologies (INCDTIM), Cluj-Napoca, 65-103 Donath str., 400293, Cluj-Napoca, Romania   Fax: +40(264)590818   eMail: igrosu@chem.ubbcluj.ro   eMail: crina.socaci@itim-cj.ro
,
Ion Grosu*
a   Babeş-Bolyai University, Supramolecular Organic and Organometallic Chemistry Center (SOOMCC), Cluj-Napoca, 11 Arany Janos str., 400028, Cluj-Napoca, Romania
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Publikationsverlauf

Received: 19. Dezember 2013

Accepted after revision: 28. Januar 2014

Publikationsdatum:
05. März 2014 (online)


Abstract

We describe herein the synthesis and characterization of new rigid nucleobase-decorated tripodands. The synthetic strategy involves the use of new azide functionalized nucleobases (adenine, thymine, and uracil). ES(+)-MS studies of hydrogen-bonding self-association as well as associations with complementary nucleosides are also reported.

Supporting Information