Synthesis of 2,3-Unsaturated Glycosides and Disaccharides via Ruthenium(III)­ Chloride Catalyzed Ferrier Glycosylation

Abstract

A facile and stereoselective method for Ferrier glycosylation was developed using ruthenium(III) chloride. Using this protocol, the glycal donor reacted smoothly with several acceptors comprising different functionalities to afford corresponding 2,3-unsaturated glycosides in good to excellent yields.

Key words

glycosylation - glycosides - stereoselective synthesis - Ferrier reaction - glycal

• References

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