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Synthesis 2015; 47(16): 2317-2346
DOI: 10.1055/s-0034-1378852
DOI: 10.1055/s-0034-1378852
review
Coinage-Metal-Catalyzed Reactions of Propargylic Alcohols
Further Information
Publication History
Received: 11 December 2014
Accepted after revision: 24 April 2015
Publication Date:
04 August 2015 (online)
Abstract
Propargylic alcohols, which possess inherent alkynyl and hydroxyl functional groups, are one of the most valuable bifunctional building blocks in the field of organic synthesis. The simple generation and conversion of these compounds into various valuable products make propargylic alcohols a powerful tool for synthetic organic chemists. These conversions have been largely achieved using transition-metal-catalytic systems, especially those using coinage metals (i.e., copper, silver and gold). However, few reviews focusing on these transformations have been published. This review summarizes the chemistry of propargylic alcohol moiety based reactions controlled by coinage-metal-catalytic systems.
1 Introduction
2 Nucleophilic Substitution Reactions
3 Rearrangement Reactions
4 Cyclization Reactions
5 Miscellaneous Reactions
6 Conclusion
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For selected recent examples, see:
Some reviews on coinage-metal-catalyzed reactions: