Chromatography-Free and Eco-Friendly Synthesis of Aryl Tosylates and Mesylates

Xiangyang Lei; Anusha Jalla; Mhd A. Abou Shama; Jamie M. Stafford; Billy Cao

doi:10.1055/s-0034-1378867

Synthesis, Table of Contents

Synthesis 2015; 47(17): 2578-2585
DOI: 10.1055/s-0034-1378867

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Chromatography-Free and Eco-Friendly Synthesis of Aryl Tosylates and Mesylates

Xiangyang Lei*

Department of Chemistry and Biochemistry, Lamar University, Beaumont, TX 77710, USA Email: xlei@lamar.ed

,

Anusha Jalla

Department of Chemistry and Biochemistry, Lamar University, Beaumont, TX 77710, USA Email: xlei@lamar.ed

,

Mhd A. Abou Shama

Department of Chemistry and Biochemistry, Lamar University, Beaumont, TX 77710, USA Email: xlei@lamar.ed

,

Jamie M. Stafford

Department of Chemistry and Biochemistry, Lamar University, Beaumont, TX 77710, USA Email: xlei@lamar.ed

,

Billy Cao

Department of Chemistry and Biochemistry, Lamar University, Beaumont, TX 77710, USA Email: xlei@lamar.ed

› Author Affiliations

Abstract

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Abstract

Two chromatography-free and eco-friendly protocols have been developed to synthesize aryl tosylates and mesylates by the tosylation and mesylation of the corresponding hydroxyarenes, respectively. These protocols are superior to other known ones regarding the simplicity, reaction time and conditions, the range of substrates, yields, and environmental friendliness.

Key words

aryl tosylates - aryl mesylates - tosylation - mesylation - green chemistry

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References

References

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