Synthesis of Acyclic and Cyclic Sulfamates: A Review

Abstract

This review surveys literature methods for the synthesis of sulfamates. The synthesis of a broad number of cyclic sulfamates (sulf­amidates) in recent years is highlighted.

1 Introduction

2 Synthesis of Acyclic Sulfamates

2.1 From Alcohols and Phenols

2.2 From Imidazolylsulfonates

2.3 From Olefins

2.4 From Isothiazole Dioxides

3 Synthesis of Cyclic Sulfamates (Sulfamidates)

3.1 From Diols and Epoxides

3.2 From Amino Alcohols

3.3 By Rhodium- and Ruthenium-Catalyzed Intramolecular Amination of Sulfamates

3.4 From Cyclic Sulfamate Imines

3.5 From the Sulfamoyl Aziridine Moiety

3.6 From Aziridines

3.7 Using Metallonitrene/Alkyne Metathesis

4 Conclusions

Key words

sulfamates - Burgess reagent - rhodium catalyst - ruthenium catalyst - sulfamoyl aziridine - metathesis - C–H amination

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