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Synthesis 2015; 47(19): 2931-2936
DOI: 10.1055/s-0034-1380418
DOI: 10.1055/s-0034-1380418
special topic
Palladium-Catalyzed Allylic Amination of Homoallylic Alcohols with Amines via Carbon–Carbon Bond Cleavage
Weitere Informationen
Publikationsverlauf
Received: 22. März 2015
Accepted after revision: 13. April 2015
Publikationsdatum:
26. Mai 2015 (online)
![](https://www.thieme-connect.de/media/synthesis/201519/lookinside/thumbnails/ss-2015-c0189-st_10-1055_s-0034-1380418-1.jpg)
Abstract
An efficient approach for palladium(II) acetate catalyzed allylic amination of homoallylic alcohols with various amines via sequential retro-allylation and amination was developed, which afforded the corresponding allylic amines in up to 98% yield.
Key words
C–C bond activation - allylic amination - homoallylic alcohols - palladium - allylic aminesSupporting Information
- Supporting information for this article is available online at http://dx.doi.org/10.1055/s-0034-1380418.
- Supporting Information
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