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Synlett 2016; 27(08): 1255-1261
DOI: 10.1055/s-0035-1561443
DOI: 10.1055/s-0035-1561443
letter
A Polycyclic Aromatic Hydrocarbon Bearing an All-cis Tetrabenzo[5.5.5.5]fenestrane (Fenestrindane) Core Merged with Two Hexa-peri-hexabenzocoronene Units
Weitere Informationen
Publikationsverlauf
Received: 10. März 2016
Accepted after revision: 29. März 2016
Publikationsdatum:
18. April 2016 (online)
![](https://www.thieme-connect.de/media/synlett/201608/lookinside/thumbnails/st-2016-u0170-l_10-1055_s-0035-1561443-1.jpg)
Dedicated to Prof. T.-Y. Luh of National Taiwan University on the occasion of his 70th birthday
Abstract
The successful merging of two multiply tert-butylated hexa-peri-hexabenzocoronene (HBC) units with all-cis-tetrabenzo[5.5.5.5]-fenestrane (fenestrindane) at two opposite aromatic rings was described. Due to steric inhibition of the tert-butyl substituents near the merging region with the fenestrindane core, attempts to construct a highly warped but fully conjugated polycyclic aromatic hydrocarbon that contains two cycloheptatriene rings failed to materialize.
Supporting Information
- Supporting information for this article is available online at http://dx.doi.org/10.1055/s-0035-1561443.
- Supporting Information
-
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For reviews of fenestranes, see: