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Synthesis 2016; 48(11): 1711-1718
DOI: 10.1055/s-0035-1561579
DOI: 10.1055/s-0035-1561579
paper
Alternative Protocol for the Synthesis of Symmetrical Dibenzyl Diselenides and Disulfides
Further Information
Publication History
Received: 12 December 2015
Accepted after revision: 15 February 2016
Publication Date:
22 March 2016 (online)
Abstract
A one-pot protocol for the preparation of symmetrical dibenzyl diselenides and disulfides from the corresponding benzyl alcohols employing NaBH2Se3 and NaBH2S3 as selenium-transfer and sulfur-transfer reagent, respectively, is described. Structurally diverse substituted benzyl alcohols afforded the corresponding diselenides and disulfides in good to excellent yields. The protocol is simple and mild, and the products were obtained within a short reaction time.
Key words
dibenzyl diselenides - dibenzyl disulfides - benzyl alcohols - selenating agent - NaBH2Se3 - NaBH2S3Supporting Information
- Supporting information for this article is available online at http://dx.doi.org/10.1055/s-0035-1561579.
- Supporting Information
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