Substrate-Assisted Carbon Dioxide Activation as a Versatile Approach for Heterocyclic Synthesis

Abstract

The incorporation of CO₂ into substrates containing alcohol or amine functional groups displays interesting substrate-controlled reactivity, both in terms of providing milder reaction conditions and the potential towards new reactivity modes. Various heterocyclic structures can be prepared using this substrate-driven approach starting from functional derivatives of (homo)allylic and propargylic alcohols/amines, epoxy alcohols, and hydroxy-oxetanes among others. This review summarizes the recent advances made in this area.

1 Introduction

2 Catalytic Conversion of Propargylic Alcohols

3 Catalytic Conversion of Propargylic Amines

4 Homoallylic and Allylic Alcohol Substrate Conversions

5 Transformation of Allylic Amines

6 Epoxy Alcohols/Amines as Substrates

7 Hydroxy-Substituted Oxetane and Azetidine Scaffolds

8 Conversion of Other Substrates

9 Summary and Outlook

Key words

amine - alcohols - carbon dioxide - heterocycles - homogeneous catalysis - substrate activation

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