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Synthesis 2017; 49(01): 151-158
DOI: 10.1055/s-0036-1588305
DOI: 10.1055/s-0036-1588305
paper
Chiral Gold Complex Catalyzed Tandem Dehydrative Cyclization/Hetero-Diels–Alder Reaction
Weitere Informationen
Publikationsverlauf
Received: 30. Juni 2016
Accepted after revision: 07. August 2016
Publikationsdatum:
09. September 2016 (online)
![](https://www.thieme-connect.de/media/synthesis/201701/lookinside/thumbnails/ss-2016-z0469-op_10-1055_s-0036-1588305-1.jpg)
Abstract
A tandem dehydrative cyclization/aza-hetero-Diels–Alder reaction catalyzed by gold(I) complex bearing BINOL-derived chiral phosphoramidite ligand has been developed. With this method, optically active chiral bicyclic tetrahydropyridazine derivatives could be obtained in one step from readily available starting materials.
Supporting Information
- Supporting information for this article is available online at http://dx.doi.org/10.1055/s-0036-1588305.
- Supporting Information
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