Synlett 2017; 28(17): 2277-2280
DOI: 10.1055/s-0036-1588473
letter
© Georg Thieme Verlag Stuttgart · New York

Synthesis of Ring-Opened Analogues of Oxysterol-Binding Protein-Inhibiting Piperidinyl-thiazole Fungicides

Sarah Sulzer-Mosse
a   Syngenta Crop Protection AG, Chemical Research, Schaffhauserstrasse 101, 4332 Stein, Switzerland   Email: clemens.lamberth@syngenta.com
,
Clemens Lamberth*
a   Syngenta Crop Protection AG, Chemical Research, Schaffhauserstrasse 101, 4332 Stein, Switzerland   Email: clemens.lamberth@syngenta.com
,
Peter Kubizna
b   Synkola s.r.o., Mlynska dolina (CH-2), Ilkovičova 6, 84215 Bratislava, Slovak Republic
› Author Affiliations
Further Information

Publication History

Received: 07 March 2017

Accepted after revision: 20 May 2017

Publication Date:
29 June 2017 (online)


Abstract

Novel aminoethyl-, aminopropyl-, and aminobutyl-substituted thiazole-4-carboxamides have been prepared which are ring-opened analogues of piperidinyl-thiazole fungicides. Depending of the chain length, completely different synthetic approaches had to be chosen which vary from a Sonogashira coupling with a 2-bromothiazole derivative to a thiazole ring construction from different β- and δ-amino acids.

Supporting Information