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Synthesis 2017; 49(16): 3511-3534
DOI: 10.1055/s-0036-1588481
DOI: 10.1055/s-0036-1588481
review
Recent Advances in Reactions of Heteroatom-Centered Radicals
This work was supported by MEXT/JSPS KAKENHI Grant-in-Aid for Scientific Research (C) (Grant No. 16K08159).Weitere Informationen
Publikationsverlauf
Received: 27. Februar 2017
Accepted after revision: 05. April 2017
Publikationsdatum:
26. Juli 2017 (online)
Abstract
Heteroatom-centered radicals show versatile reactivity and offer useful synthetic methods in organic chemistry. The development of new approaches for forming heteroatom-centered radicals has recently expanded the practicality of radical chemistry for synthesis. This review focuses on recent advances in reactions of representative heteroatom-centered radicals.
1 Introduction
2 Group 17 Elements: Chlorine and Bromine Radicals
3 Group 15 and Group 16 Elements
3.1 Nitrogen- and Oxygen-Centered Radicals
3.2 Phosphorus- and Sulfur-Centered Radicals
3.3 Other Radicals
4 Group 14 Elements: Silicon-Centered Radicals
5 Group 13 Elements: Boron-Centered Radicals
6 Conclusion
-
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