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Synthesis 2017; 49(09): 2009-2014
DOI: 10.1055/s-0036-1588946
DOI: 10.1055/s-0036-1588946
paper
Synthesis of Acylsilanes via Catalytic Dedithioacetalization of 2-Silylated 1,3-Dithianes with 30% Hydrogen Peroxide
Weitere Informationen
Publikationsverlauf
Received: 09. Januar 2017
Accepted after revision: 13. Januar 2017
Publikationsdatum:
15. Februar 2017 (online)
Abstract
Acylsilanes were obtained efficiently from dedithioacetalization of 2-silylated 1,3-dithianes using 30% hydrogen peroxide catalyzed by iron(III) acetylacetonate–sodium iodide. The use of niobium(V) chloride as a catalyst instead of iron(III) acetylacetonate was also effective, except in synthesizing some acyltrimethylsilanes.
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