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DOI: 10.1055/s-0036-1591839
Recent Progress in Catalytic Enantioselective Desymmetrization of Prochiral Organosilanes for the Synthesis of Silicon-Stereogenic Compounds
Support has been provided in part by a Grant-in-Aid for Scientific Research (B) (16H04145) from the Ministry of Education, Culture, Sports, Science and Technology, Japan.Publikationsverlauf
Received: 29. September 2017
Accepted after revision: 27. Oktober 2017
Publikationsdatum:
23. November 2017 (online)
Abstract
It is highly important to develop efficient synthetic methods for various enantioenriched chiral compounds due to their high significance in our life. In this regard, asymmetric catalysis is one of the most attractive ways of synthesizing such compounds from achiral precursors. Although various methods have been developed for the enantioselective preparation of carbon-stereogenic compounds, the corresponding methods for silicon-stereogenic compounds are much less established. In particular, little progress has been made on catalytic enantioselective synthesis using prochiral organosilanes until recently. This account focuses on the recent progress in the catalytic enantioselective preparation of silicon-stereogenic organosilanes through desymmetrization of prochiral organosilanes.
1 Introduction
2 Desymmetrization of Diorganodihydrosilanes
3 Desymmetrization of Tetraorganosilanes
3.1 Desymmetrization through Cleavage of Silicon–Carbon Bonds
3.2 Desymmetrization without Cleavage of Silicon–Carbon Bonds
4 Conclusion
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For recent reviews on catalytic asymmetric synthesis of silicon-stereogenic organosilanes, see:
For non-asymmetric intermolecular precedents, see: