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Synthesis 2018; 50(03): 499-513
DOI: 10.1055/s-0036-1591853
DOI: 10.1055/s-0036-1591853
short review
Recent Advances in Nickel Catalysis Enabled by Stoichiometric Metallic Reducing Agents
This work was supported in part by a LabEx CSC ‘Chemistry of Complex Systems’ grant and from the European Research Council (ERC) under the European Union’s Horizon 2020 research and innovation programme (grant agreement no 639170).Further Information
Publication History
Received: 29 September 2017
Accepted after revision: 07 November 2017
Publication Date:
14 December 2017 (online)
Abstract
This short review describes recent advances in the field of nickel catalysis, specifically transformations employing stable Ni(II) precatalysts that are activated in situ with the use of stoichiometric metallic reducing agents. The article seeks to summarise the field, highlighting key studies and discussing mechanistic facets. The review closes with an eye on future directions in redox-enabled nickel catalysis.
1 Introduction
2 Nickel Catalysis Enabled by Metallic Reducing Agents
3 Reductive Cross-Coupling
4 Reductive Carboxylation and Acylation-type reactions
5 Miscellaneous Reactivity
6 Perspectives and Future Directions
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For reviews, see:
For leading references, see:
For leading examples, see:
The use of silanes as terminal reductants in nickel catalysis has been investigated. For a recent example, see:
For recent seminal examples of silanes as terminal reducing agents in cross-coupling manifolds, see: