Selective Semi-Hydrogenation of Terminal Alkynes Promoted by Bimetallic Cu-Pd Nanoparticles

Eduardo Buxaderas; María Alicia Volpe; Gabriel Radivoy

doi:10.1055/s-0037-1610318

Synthesis, Table of Contents

Synthesis 2019; 51(06): 1466-1472
DOI: 10.1055/s-0037-1610318

paper

Selective Semi-Hydrogenation of Terminal Alkynes Promoted by Bimetallic Cu-Pd Nanoparticles

Eduardo Buxaderas

^aInstituto de Química del Sur (INQUISUR-CONICET), Departamento de Química, Universidad Nacional del Sur, Avda. Alem 1253, 8000 Bahía Blanca, Argentina Email: gradivoy@criba.edu.ar

,

María Alicia Volpe

^bPlanta Piloto de Ingeniería Química, PLAPIQUI (CONICET-UNS), Camino La Carrindanga Km 7, CC 717, 8000 Bahía Blanca, Argentina

,

Gabriel Radivoy*

^aInstituto de Química del Sur (INQUISUR-CONICET), Departamento de Química, Universidad Nacional del Sur, Avda. Alem 1253, 8000 Bahía Blanca, Argentina Email: gradivoy@criba.edu.ar

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Abstract

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Abstract

The selective semi-hydrogenation of terminal alkynes was efficiently performed, under mild reaction conditions (H₂ balloon, 110 °C), promoted by a bimetallic nanocatalyst composed of copper and palladium nanoparticles (5:1 weight ratio) supported on mesostructured silica (MCM-48). The Cu-PdNPS@MCM-48 catalyst, which demonstrated to be highly chemoselective towards the alkyne functionality, is readily prepared from commercial materials and can be recovered and reused after thermal treatment followed by reduction under H₂ atmosphere.

Key words

alkynes - semi-hydrogenation - heterogeneous catalysis - bimetallic nanoparticles - copper - palladium

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References

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