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Synthesis 2019; 51(06): 1466-1472
DOI: 10.1055/s-0037-1610318
DOI: 10.1055/s-0037-1610318
paper
Selective Semi-Hydrogenation of Terminal Alkynes Promoted by Bimetallic Cu-Pd Nanoparticles
This work was generously supported by the Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET, PIP-2011-268), Agencia Nacional de Promoción Científica y Tecnológica (ANPCyT, Prest. BID, PICT-2014-2171), and Universidad Nacional del Sur (UNS, PGI 24/Q072) from Argentina.Further Information
Publication History
Received: 18 September 2018
Accepted after revision: 15 October 2018
Publication Date:
21 November 2018 (online)
Abstract
The selective semi-hydrogenation of terminal alkynes was efficiently performed, under mild reaction conditions (H2 balloon, 110 °C), promoted by a bimetallic nanocatalyst composed of copper and palladium nanoparticles (5:1 weight ratio) supported on mesostructured silica (MCM-48). The Cu-PdNPS@MCM-48 catalyst, which demonstrated to be highly chemoselective towards the alkyne functionality, is readily prepared from commercial materials and can be recovered and reused after thermal treatment followed by reduction under H2 atmosphere.
Key words
alkynes - semi-hydrogenation - heterogeneous catalysis - bimetallic nanoparticles - copper - palladiumSupporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0037-1610318.
- Supporting Information
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