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Synlett 2018; 29(16): 2181-2184
DOI: 10.1055/s-0037-1610630
DOI: 10.1055/s-0037-1610630
letter
Cobalt Vanadium Oxide Supported on Reduced Graphene Oxide for the Oxidation of Styrene Derivatives to Aldehydes with Hydrogen Peroxide as Oxidant
Further Information
Publication History
Received: 20 June 2018
Accepted after revision: 06 August 2018
Publication Date:
30 August 2018 (online)
Abstract
Cobalt vanadium oxide supported on reduced graphene oxide showed excellent performance in the oxidation of styrene derivatives to the corresponding aldehydes with hydrogen peroxide as oxidant. An electron-donating group at the para-position of the aromatic ring facilitates the formation of the corresponding aldehyde. Compared with conventional methods, the newly designed heterogeneous catalytic system offers a promising prospect because of its economic applicability and environmental friendliness.
Key words
cobalt vanadium oxide - reduced graphene oxide - styrene oxidation - hydrogen peroxide - styrene derivatives - aldehydesSupporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0037-1610630.
- Supporting Information
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- 15 Typical Procedure The oxidation of styrene derivatives was carried out in a 50 mL two-necked round-bottomed flask. Substrate (1 mmol) was stirred with the CoV catalyst (0.02 g) in MeCN (5.0 mL). 30 wt% H2O2 (0.34 g) was added slowly to the mixture, the temperature was increased to 65 °C, and the mixture was stirred for 6 h. The catalyst was separated by centrifugation and the product was extracted with EtOAc and sat. aq NaCl. The organic phase was dried (Na2SO4) and purified by column chromatography.Benzaldehyde (Table 2, entry 16): Colorless liquid; to give a colorless liquid; yield: 91 mg (91%). 1H NMR (500 MHz, CDCl3); δ = 10.08 (s, 1 H), 7.98–7.91 (m, 2 H), 7.69 (t, J = 7.4 Hz, 1 H), 7.59 (t, J = 7.6 Hz, 2 H). 13C NMR (126 MHz, CDCl3); δ = 191.87, 135.96, 133.98, 129.24, 128.53.