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Synlett 2019; 30(12): 1427-1430
DOI: 10.1055/s-0037-1611846
DOI: 10.1055/s-0037-1611846
letter
Tricyanomethane and its Salts with Nitrogen Bases: A Correction of Sixteen Reports
Further Information
Publication History
Received: 29 March 2019
Accepted after revision: 10 May 2019
Publication Date:
05 June 2019 (online)
Abstract
A series of 16 articles, dealing with formation of tricyanomethanide salts from nitrogen bases (amines) and tricyanomethane, turned out to be wrong because no tricyanomethane or similar compounds are used and no tricyanomethanide salts are prepared. This statement is based mainly on the recently published spectroscopic data and depicted spectra, which are completely incompatible with the claimed structures. Some of the tricyanomethanide salts are now synthesized from nitrogen heterocycles and tricyanomethane or other precursors. The corresponding products show plausible spectroscopic data and physical properties, which are entirely different to those previously reported.
Key words
exclusion of structures - spectroscopic characterization - tricyanomethane - tricyanomethanide salts - unstable compoundsSupporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0037-1611846.
- Supporting Information
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References and Notes
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