A Practical Synthesis of Ammonia from Nitrogen Gas, Samarium Diiodide and Water Catalyzed by a Molybdenum–PCP Pincer Complex

Yuya Ashida; Shoichi Kondo; Kazuya Arashiba; Takamasa Kikuchi; Kazunari Nakajima; Seizo Kakimoto; Yoshiaki Nishibayashi

doi:10.1055/s-0039-1690151

Synthesis, Inhaltsverzeichnis

Synthesis 2019; 51(20): 3792-3795
DOI: 10.1055/s-0039-1690151

psp

A Practical Synthesis of Ammonia from Nitrogen Gas, Samarium Diiodide and Water Catalyzed by a Molybdenum–PCP Pincer Complex

Yuya Ashida

^aDepartment of Systems Innovation, School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo, 113-8656, Japan eMail: ynishiba@sys.t.u-tokyo.ac.jp

,

Shoichi Kondo

^bMaterials Research Laboratories, Nissan Chemical Corporation, Funabashi-shi, Chiba, 274-0052, Japan

,

Kazuya Arashiba

^aDepartment of Systems Innovation, School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo, 113-8656, Japan eMail: ynishiba@sys.t.u-tokyo.ac.jp

,

Takamasa Kikuchi

^bMaterials Research Laboratories, Nissan Chemical Corporation, Funabashi-shi, Chiba, 274-0052, Japan

,

Kazunari Nakajima

^cFrontier Research Center for Energy and Resources, School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo, 113-8656, Japan

,

Seizo Kakimoto

^dAdvanced Materials & Planning Department, Nissan Chemical Corporation, Nihonbashi, Chuo-ku, Tokyo, 103-6119, Japan

,

Yoshiaki Nishibayashi ∗

^aDepartment of Systems Innovation, School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo, 113-8656, Japan eMail: ynishiba@sys.t.u-tokyo.ac.jp

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Abstract

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Abstract

A practical method for ammonia synthesis is described. The reaction of atmospheric pressure of nitrogen gas with samarium diiodide as a reducing reagent and water as a proton source in the presence of a catalytic amount of a molybdenum trichloride complex bearing a PCP [1,3-bis(di-tert-butylphosphinomethyl)benzimidazol-2-ylidene]-type pincer ligand occurs under ambient conditions to afford ammonium sulfate after treatment with sulfuric acid.

Key words

ammonia - dinitrogen - molybdenum - samarium diiodide - water

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Referenzen

References
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