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Synlett 2019; 30(19): 2181-2184
DOI: 10.1055/s-0039-1690221
DOI: 10.1055/s-0039-1690221
letter
Copper(I)-Catalyzed Sulfenylation of 1,3-Dicarbonyl Substrates with Disulfides under Mild Conditions
We would like to thank the National Natural Science Foundation of China (grant numbers 21476041, U1608224, 61633006) and the State Key Laboratory of Fine Chemicals for their support.Further Information
Publication History
Received: 28 August 2019
Accepted after revision: 10 October 2019
Publication Date:
23 October 2019 (online)
Abstract
A copper(I) iodine catalyzed sulfenylation of 1,3-dicarbonyl substrates in the presence of MeCN is presented. Various β-keto esters and β-keto amide substrates can react with disulfides to afford their corresponding products in good to excellent yields. The notable features of this protocol include high atom economy, easy operation, mild reaction conditions, and excellent functional group tolerance.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0039-1690221.
- Supporting Information
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