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Synthesis 2020; 52(13): 1969-1980
DOI: 10.1055/s-0039-1690848
DOI: 10.1055/s-0039-1690848
paper
Co(II)-Catalyzed Desilylative Annulation of Benzamides and Acrylamides with Alkynylsilanes: Access to 3-Methyleneisoindolin-1-one and 5-Methylene-1H-pyrrol-2(5H)-one Derivatives
Funding from Natural Science Foundation of China (No. 51963010 and 21704036) and Science Funds of the Education Office of Jiangxi Province (No. GJJ180601) is acknowledged.Weitere Informationen
Publikationsverlauf
Received: 02. Dezember 2019
Accepted after revision: 13. Februar 2020
Publikationsdatum:
03. März 2020 (online)
§ These authors contributed equally.
Abstract
The cobalt-catalyzed desilylative annulation of C(sp2)–H bonds of benzamides and acrylamides with alkynylsilanes assisted by an 8-aminoquinolyl directing group is reported. A variety of benzamides and acrylamides were compatible in this protocol to construct various 3-methyleneisoindolin-1-one and 5-methylene-1H-pyrrol-2(5H)-one derivatives with Z-configuration selectivity in moderate to high yields.
Key words
cobalt catalysis - desilylative annulation - benzamides and acrylamides - alkynylsilanes - 3-methyleneisoindolin-1-one - 5-methylene-1H-pyrrol-2(5H)-oneSupporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0039-1690848.
- Supporting Information
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