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Synthesis 2019; 51(23): 4425-4433
DOI: 10.1055/s-0039-1690984
DOI: 10.1055/s-0039-1690984
paper
Nitroacenaphthene as a New Photocatalyst for the Synthesis of Sulfonyl Amidines
We are grateful for the financial support from the National Natural Science Foundation of China (No. 21672047), State Key Laboratory of Urban Water Resource and Environment (SKLUWRE, No. 2018DX02) and the Science and Technology Planning Project of Shenzhen Municipality (No. JCYJ20180306172044124).Further Information
Publication History
Received: 18 July 2019
Accepted after revision: 20 August 2019
Publication Date:
13 September 2019 (online)
Abstract
A small molecule, namely nitroacenaphthene, is reported for the first time as a recyclable visible-light photocatalyst for the construction of the C=N bond from sulfonyl azides and amines. This scalable, site-selective protocol provides a convenient way to access various sulfonyl amidines under mild conditions. Two reaction pathways are proposed, according to different transformation patterns.
Key words
nitroacenaphthene - photocatalyst - carbon-nitrogen double bond - sulfonyl amidines - N′-sulfonylimidamides - site selectivitySupporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0039-1690984.
- Supporting Information
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