Synlett 2021; 32(02): 109-118
© Georg Thieme Verlag Stuttgart · New York
[(bpy)CuSCF3 ]: A Practical and Efficient Reagent for the Construction of C–SCF3 Bonds
Yangjie Huang
a
Fujian Engineering Research Center of New Chinese lacquer Material, Ocean College, Minjiang University, Fuzhou, 350108, P. R. of China
,
Mengjia Zhang
b
Fujian Provincial Key Laboratory of Electrochemical Energy Storage Materials, College of Chemistry, Fuzhou University, Fuzhou, 350108, P. R. of China Email:
zweng@fzu.edu.cn
,
Qi Lin∗
a
Fujian Engineering Research Center of New Chinese lacquer Material, Ocean College, Minjiang University, Fuzhou, 350108, P. R. of China
,
Zhiqiang Weng∗
a
Fujian Engineering Research Center of New Chinese lacquer Material, Ocean College, Minjiang University, Fuzhou, 350108, P. R. of China
b
Fujian Provincial Key Laboratory of Electrochemical Energy Storage Materials, College of Chemistry, Fuzhou University, Fuzhou, 350108, P. R. of China Email:
zweng@fzu.edu.cn
› Author Affiliations This work was supported by the National Natural Science Foundation of China (grant numbers 21372044 and 21772022), Fuzhou University, and Minjiang University.
Abstract
In this account, we summarize recent work on the direct introduction of the SCF3 group by using [(bpy)CuSCF3 ] as trifluoromethylthiolating reagent. A number of efficient and convenient strategies have been disclosed for the synthesis of trifluoromethylthiolated compounds, including trifluoromethylthiolation of aryl, alkenyl, and alkyl halides, and arylboronic acids. These reactions afford various trifluoromethyl sulfides in good yields.
1 Introduction
2 Synthesis of [(bpy)CuSCF3 ]
3 Trifluoromethylthiolation of Aryl Halides
4 Trifluoromethylthiolation of Alkenyl Halides
5 Trifluoromethylthiolation of Alkyl Halides
6 Miscellaneous
7 Conclusion
Key words
trifluoromethylthiolation -
copper -
fluorine -
trifluoromethylthiolating reagent
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