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DOI: 10.1055/s-0040-1719893
Current Advances in Meerwein-type Radical Alkene Functionalizations
The authors are grateful for the support of their research work by the Deutsche Forschungsgemeinschaft (DFG, HE 5413/9-4).
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Abstract
Alkene functionalizations via Meerwein arylations are becoming increasingly attractive, especially since a variety of mild and sustainable methods for aryl radical generation are available today. This entails a broad spectrum of substrates and radical scavengers, as well as convenient synthetic routes to relevant precursors for further transformations. The present review focuses on recent advances in Meerwein-type alkene functionalizations and gives insights into the key mechanistic details of the respective reactions.
1 Introduction
2 Hydroarylation and Carboarylation
3 Carboamination, Carbooxygenation, and Carbothiolation
4 Carbohalogenation
5 Conclusion and Outlook
Key words
Meerwein arylation - radical chemistry - photocatalysis - olefins - radical-polar crossoverPublikationsverlauf
Eingereicht: 08. November 2021
Angenommen nach Revision: 08. Dezember 2021
Artikel online veröffentlicht:
02. März 2022
© 2022. Thieme. All rights reserved
Georg Thieme Verlag KG
Rüdigerstraße 14, 70469 Stuttgart, Germany
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