Taming SbH3: A Simple and Safe Approach to Using Stibane in Synthesis on a Laboratory Scale

Kevin Dollberg; Selina Schneider; Carsten von Hänisch

doi:10.1055/s-0042-1751441

Synlett, Table of Contents

Synlett 2023; 34(15): 1777-1780
DOI: 10.1055/s-0042-1751441

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Taming SbH₃: A Simple and Safe Approach to Using Stibane in Synthesis on a Laboratory Scale

Kevin Dollberg

,

Selina Schneider

,

Carsten von Hänisch ∗

Abstract

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Abstract

Herein, we present a simple, inexpensive, and readily accessible apparatus for the safe and clean preparation, isolation, and conversion of stibane (SbH₃). In this setup, only typical standard glassware and fabric tubes are used. The pure stibane can be obtained in very good yields with very little expenditure of time.

Key words

antimony - stibane - inorganic chemistry - vacuum synthesis - gas induction

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References

References
1 Hollemann AF, Wiberg E. Lehrbuch der Anorganischen Chemie . De Gruyter; Berlin: 2007
2 Gengembre P. Crells Chemische Annalen 1789; 11: 450
3 Brauer G. Handbuch der Präparativen Anorganischen Chemie. Ferdinand Enke; Stuttgart: 1975
4 Ostwald W. GB190200698, 1902
5 Raschig F. Chem. Ber. 1907; 40: 4580
6 Bettermann G, Krause W, Riess G, Hofmann T. Ullmann’s Encyclopedia of Industrial Chemistry. Wiley; Hoboken: 2012: 1
7 Yu P, Cardona M. Fundamentals of Semiconductors Physics and Materials Properties. Springer; Heidelberg: 2005
8 Macfarlane DR, Cherepanov PV, Choi J, Suryanto BH. R, Hodgetts RY, Bakker JM, Vallana FM. F, Simonov AN. Joule 2020; 4: 1186
9 Warren EL, Kibbler AE, France RM, Warren EL, Kibbler AE, France RM, Norman AG, Stradins P, Mcmahon WE. Appl. Phys. Lett. 2015; 107: 082109
10 Hood TM, Lau S, Webster RL. J. Am. Chem. Soc. 2022; 144: 16684
11 Driess M, Monsé C. Z. Anorg. Allg. Chem. 2000; 626: 1091
12 Cowley AH, Harris PR, Jones RA, Nunn CM. Organometallics 1991; 10: 652
13 Schneider S, Ivlev S, von Hänisch C. Chem. Commun. 2021; 57: 3781
14 Atwood DA, Cowley AH, Harris PR, Jones RA, Koschmieder SU, Nunn CM, Atwood JL, Bott SG. Organometallics 1993; 12: 24
15 Yao S, Grossheim Y, Kostenko A, Ballestero-Martínez E, Schutte S, Bispinghoff M, Grützmacher H, Driess M. Angew. Chem. Int. Ed. 2017; 56: 7465
16 Weinhardt MA. K, Lisovenko AS, Timoshkin AY, Scheer M. Angew. Chem. Int. Ed. 2020; 59: 5541
17 Weinhardt MA. K, Seidl M, Timoshikin AY, Scheer M. Angew. Chem. Int. Ed. 2021; 60: 3806
18 Präsang C, Stoelzel M, Inoue S, Meltzer A, Driess M. Angew. Chem. Int. Ed. 2010; 49: 10002
19 Fritz G, Scheer P. Chem. Rev. 2000; 100: 3341
20 Schäfer H, Fritz G. Z. Anorg. Allg. Chem. 1977; 428: 222
21 William L, Jolly L. J. Am. Chem. Soc. 1959; 81: 1029
22 Lapshin IV, Cherkasov AV, Lyssenko KA, Fukin GK, Trifonov AA. Inorg. Chem. 2022; 61: 9147
23 Thomson L. J. Prakt. Chem. 1837; 11: 369
24 Pfaff CM. Pogg. Ann. 1837; 42: 339
25 Simon JF. Pogg. Ann. 1837; 42: 563
26 Jones F. J. Chem. Soc. 1876; 26: 641
27 Stock A, Doht W. Ber. Dtsch. Chem. Ges. 1901; 34: 2339
28 Stock A, Guttmann O. Ber. Dtsch. Chem. Ges. 1904; 37: 885
29 Sand HJ. S, Weeks EJ, Worrell SW. J. Chem. Soc. 1923; 123: 456
30 Wiberg E, Mödritzer KZ. Naturforsch., B: Anorg. Chem., Org. Chem., Biochem., Biophys., Biol. 1957; 12: 123
31 Todd M, Bandari G, Baum T. Chem. Mater. 1999; 11: 547
32 Olschewski K. Ber. Dtsch. Chem. Ges. 1901; 34: 3592
33 Dollberg K, Schneider S, Richter R, Dunaj T, von Hänisch C. Angew. Chem. Int. Ed. 2022; 61: e202213098

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