Functionalized Aza-BODIPYs and Their Use in the Synthesis of Aza-BODIPY-Based Complex Systems

Abstract

In this account, we present syntheses of various functionalized aza-boron-dipyrromethene dyes (aza-BODIPYs) in which the functional groups are directly introduced at the 2- or 6-positions of the aza-BODIPYs or on aryl rings present at the 1-, 3-, 5-, and 7-positions of the aza-BODIPYs. Some of these functionalized aza-BODIPYs have been used for the synthesis of aza-BODIPY-based energy-transfer cassettes and light-harvesting complexes.

1 Introduction

2 Monofunctionalized Aza-BODIPYs

2.1 2-/6-Monofunctionalized Aza-BODIPYs

2.2 1-/3-/5-/7-Monofunctionalized Aza-BODIPYs

3 Difunctionalized Aza-BODIPYs.

3.1 2,6-Difunctionalized Aza-BODIPYs

3.2 3,5-Difunctionalized Aza-BODIPYs

3.3 1,7-Difunctionalized Aza-BODIPYs

4 Miscellaneous

5 Conclusion

Key words

azadipyrromethene–boron difluoride complexes - BODIPYs - aza-BODIPYs - dyes - energy-transfer cassettes - light harvesting

Publication History

Received: 20 March 2023

Accepted after revision: 19 June 2023

Article published online:
17 August 2023

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