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Synlett 1989; 1989(1): 52-54
DOI: 10.1055/s-1989-34703
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Stereoselective Synthesis of Homoallylic Alcohols by Migratory Insertion Reactions of Higher-Order Cyanocuprates and Nickel-Catalysed Coupling Reactions Involving Enol Carbamates

Philip Kocienski* , Nicholas J. Dixon
  • *Chemistry Department, The University, Southampton, SO9 5NH, England
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Publication Date:
26 February 2002 (online)

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A combination of metalation, copper-catalysed migratory insertion reactions, and nickel-catalysed coupling reactions can be used to introduce two new C-C bonds or one C-C and one C-metal bond onto the enol carbarnate moiety of 4-hydroxy-1-en-1-ol carbamates.