Indirect Electrooxidation of Alcohols by a Double Mediatory System with  [R2N+ = O]/R2N-O . and [Br. or Br+ ]Br- Redoxes

Tsutomu Inokuchi; Sigeaki Matsumoto; Tokio Nisiyama; Sigeru Torii

doi:10.1055/s-1990-20988

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Synlett 1990; 1990(1): 57-58
DOI: 10.1055/s-1990-20988

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Indirect Electrooxidation of Alcohols by a Double Mediatory System with [R₂N⁺ = O]/R₂N-O . and [Br. or Br⁺ ]Br^- Redoxes

Tsutomu Inokuchi^* , Sigeaki Matsumoto, Tokio Nisiyama, Sigeru Torii

^*Department of Applied Chemistry, Faculty of Engineering, Okayama University, Okayama 700, Japan

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Publikationsdatum:
08. März 2002 (online)

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A double mediatory system consisting of N-oxoammonium salts and active bromine species, generated from 2,2,6,6-tetramethylpiperidine-1-oxyl derivatives and bromide ion as recyclable reagents, is useful for the selective electrooxidation of primary and secondary alcohols to aldehydes and ketones, respectively, in an aqueous-organic two-phase system.