PDF herunterladen
Synlett 1990; 1990(5): 245-250
DOI: 10.1055/s-1990-21050
account
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Metalation of Isocyanides

Yoshihiko Ito* , Masahiro Murakami
  • *Department of Synthetic Chemistry, Faculty of Engineering, Kyoto University, Yoshida, Kyoto 606, Japan
Weitere Informationen

Publikationsverlauf

Publikationsdatum:
08. März 2002 (online)

  als PDF herunterladen  Lizenzen und Reprints Alle Artikel dieser Rubrik

Metalation of isocyanides is achieved by an insertion of isocyanides into metal-metal or metal-carbon linkage of a variety of organometallic compounds giving the corresponding N-substituted (α-iminoalkyl)metal compounds. Synthetic applicabilities of N-substituted (α-iminoalkyl)metal compounds thus formed are demonstrated. 1. Introduction 2. Bis-metalation of Isocyanides with Organosilylstannanes 3. Bis-metalation of Isocyanides with Organopolysilanes 4. Mono-metalation of Isocyanides with Organozinc Reagents 5. Mono-metalation of Isocyanides with Organosamarium Reagents 6. Synthesis of Quinoxaline Oligomers by Reaction of o-Diisocyanoarenes with Grignard Reagents 7. Conclusion