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Synlett 1991; 1991(3): 195-197
DOI: 10.1055/s-1991-20677
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A New Synthesis of Optically Active Tetrahydropyrans and Tetrahydrofurans

Abderrahmane Teniou* , Loïc Toupet, René Grée
  • *Laboratoire de Chimie Organique Biologique CNRS URA D0704, ENSCR, Avenue du Gal Leclerc, F-35700 Rennes-Beaulieu, France
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Publication Date:
07 March 2002 (online)

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The intramolecular trapping, by suitable oxygen nucleophiles, of acyclic pentadienyl cations stabilized by an Fe(CO)3 group provides a new efficient methodology for the preparation of optically active tetrahydropyrans and tetrahydrofurans.