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Synlett 1991; 1991(4): 248-250
DOI: 10.1055/s-1991-20695
DOI: 10.1055/s-1991-20695
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Regio- and Chemoselective Ring Opening of Epoxides to Bromohydrins with Dilithium Tetrabromocuprate
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Publication History
Publication Date:
07 March 2002 (online)
Dilithium tetrabromocuprate, prepared from lithium bromide and copper(II) bromide, regioselectively converts functionalized epoxides (11 examples) to vicinal bromohydrins resulting from nucleophilic attack by bromide at the less substituted epoxide carbon.