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Synlett 1991; 1991(4): 253-254
DOI: 10.1055/s-1991-20697
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Organoaluminum-Catalyzed Transfer of Silicon from Oxygen to Carbon in Silyl Ketene Acetals

Keiji Maruoka* , Hiroshi Banno, Hisashi Yamamoto
  • *Department of Applied Chemistry, Nagoya University, Chikusa, Nagoya 464-01, Japan
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Publikationsdatum:
07. März 2002 (online)

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In the presence of a catalytic amount of trimethylaluminum, the trialkylsilyl group in silyl ketene acetals [1-alkoxy / benzyloxy / cycloalkoxy-1-(trialkylsiloxy)ethylenes] smoothly under-goes a 1,3-rearrangement from oxygen to carbon, under very mild conditions, to give (trialkylsilyl)acetic acid esters.