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Synlett 1991; 1991(7): 472-474
DOI: 10.1055/s-1991-20764
DOI: 10.1055/s-1991-20764
letter
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A Model for the Synthesis of the Tigliane and Daphnane Diterpenes Using an Intramolecular Diels-Alder Reaction
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Publication History
Publication Date:
07 March 2002 (online)
A synthesis of the tricyclo[9.3.0.02,7]tetradecane ring system of the daphnanes and tiglianes has been achieved in five steps from 2-cyclopenten-1-one using an unusual intramolecular Diels-Alder reaction as the cornerstone.