Synlett 1991; 1991(7): 477-478
DOI: 10.1055/s-1991-20766
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Hydrogen Peroxide/Vilsmeier Reagent System; Part 21: Reactivity Toward Keto-Olefins

Jean Rodriguez* , Jean-Pierre Dulcère
  • *Laboratoire de Synthèse Organique, SM3B URA 1411, Université d'Aix-Marseille III, Faculté des Sciences de St. Jérome, D12 avenue Escadrille Normandie-Niemen, F-13397 Marseille Cedex, France
Further Information

Publication History

Publication Date:
07 March 2002 (online)

The hydrogen peroxide/Vilsmeier reagent system reacts with keto-olefins 1-5 to give allylic chlorides 6-10 by an Ene-type chlorination reaction.