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Synlett 1991; 1991(7): 489-490
DOI: 10.1055/s-1991-20772
DOI: 10.1055/s-1991-20772
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Dicyclopentadienyltitanium Halide Induced Reduction of Nitroarenes and Organic Halides
Further Information
Publication History
Publication Date:
07 March 2002 (online)
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Nitroarenes are reduced by dicyclopentadienyltitanium chloride (Cp2TiCl) to azo compounds in moderate yield while benzylic and allylic chlorides and vicinal dibromides are catalytically transformed to the corresponding coupling products and alkenes, respectively, by the dicyclopentadienyltitanium dichloride/aluminum system.