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Synlett 1991; 1991(8): 555-556
DOI: 10.1055/s-1991-20794
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Synthesis of Allyloxiranes from Allyltributyltin and α-Halo Ketones Catalyzed by Dibutyltin Dihalide-Hexamethylphosphoric Triamide Complexes

Katsunori Yano* , Yukio Hatta, Akio Baba, Haruo Matsuda
  • *Department of Applied Chemistry, Faculty of Engineering, Osaka University, 2-1 Yamada-Oka, Suita, Osaka 565, Japan
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Publication Date:
07 March 2002 (online)

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Dibutyltin dihalides act as versatile catalysis in combination with hexamethylphosphoric triamide (HMPT) for the reaction of allyltributyltin and α-halo ketones, furnishing the corresponding allyloxiranes in good yield; a palladium catalyst, which is generally used, is not required.